Polymerization Vinyl Chloride
About 13 billion kilograms are produced annually.
Polymerization vinyl chloride. Pvc vinyl chloride is an organohalogen compound that has important industrial applications. Natural evolution of hcl from vc occurred in the polymerization. The alkyl group of the alkyl acrylate or alkyl methacrylate is preferably a 2 ethylhexyl group. Polyvinyl chloride is produced by polymerization of the vinyl chloride monomer vcm as shown.
Chemical and physical methods were used to observe irregular structures such as branching. Suspension and emulsion polymerization of vinyl chloride monomer using free radical initiators. Polymerization of vinyl chloride have been identified including elemen tary chemical reactions. Pvc is used in the manufacture of numerous products including packaging films and water pipes.
Physical phenomena of polyvinylchloride parti cle formation and reactant species distributions in phas s during poly merization. Vinyl chloride is an organochloride with the formula h 2 c chcl that is also called vinyl chloride monomer vcm or chloroethene this colorless compound is an important industrial chemical chiefly used to produce the polymer polyvinyl chloride pvc. Vc vc αd 1 vc β βd 2 and vc d 3 were used to study the reactivities of the hydrogen atoms in the polymerization and the β hydrogen atoms contributed to the chain transfer. Vinyl chloride ch 2 chcl is most often obtained by reacting ethylene with oxygen and hydrogen chloride over a copper catalyst.
Isopropyl chloride 2 4 dichloropentane and 2 4 6 trichloroheptane were used as solvents. The participation of chain transfer reactions in the polymerization of vinyl chloride in solutions has been elucidated. Emulsion polymerization accounts for about 12 and bulk polymerization accounts for 8. Suspension polymerization of vinyl chloride using one and two initiator systems.
Nlesc rate data were also used to test the applicapility of the rodel. A copolymer of i an alkyl acrylate or alkyl methacrylate and ii a hydroxyalkyl acrylate or hydroxyalkyl methacrylate is used as a secondary protective colloid in the suspension polymerization of vinyl chloride monomer. When treated with certain catalysts vinyl chloride monomers undergo polymerization and form the larger compound known as polyvinyl chloride or pvc. Polyvinyl chloride is produced by polymerization of the vinyl chloride monomer vcm.
Parts i and i i also include a rather extensive review of pvc r tecjmology and the variolls models that have been publ ishcd for i1klss and suspension imlymerizatiqn of vinyl chloride. It is a carcinogenic gas that must be handled with special protective procedures. Emulsion polymerization accounts for about 12 and bulk polymerization accounts for 8. Polymerization of vinyl chloride vc was studied.
A comprehensive reactor model for batch and semi batch proc esses has been developed on the basis of these. The hydroxyalkyl group of the hydroxyalkyl acrylate or hydroxyalkyl. Suspension polymerization affords particles with average diameters of 100 180 μm whereas emulsion.